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Table 1: Fuel cell types | ||||||
Cell type | Electrolyte | Operating temperature | Efficiency | Output | Applications | Disadvantages |
Alkali (AFC) | Generally potassium hydroxide in water | 150 – 200°C | 70% | 300 W – 5 kW | Used on Apollo spacecraft to provide electricity and drinking water and in prototype taxi by ZEVCO in London. | Require pure hydrogen fuel; platinum electrodes are expensive, although companies are examining ways of reducing costs; can leak. |
Molten carbonate (MCFC) | High temperature compounds of salt carbonates | 650°°ä | 60 – 80% | Up to 2 MW with 100 MW units designed | Creation of waste heat to make steam for heating, industrial processing or in steam turbines to generate more electricity. | High temperature limits materials and safe use of MCFCs – too hot for home use. Also, carbon dioxide needs to be injected to compensate for carbonate ions used in reactions. |
Phosphoric acid (PAFC) | Phosphoric acid | 150 – 200°C | 40 – 80% | Existing cells up to 200 kW; 11 MW units have been tested | Used in public transport, but limited applications in private cars as warm-up time needed. Have been used in stationary power generation. | Platinum electrode catalysts are needed and internal parts must be able to withstand acid. |
Proton exchange membrane (PEM) | Polymer electrolyte in thin permeable sheet | 80°°ä | 40 – 50% | 50 – 250 kW | Operate at low enough temperatures to be suitable for homes and cars. | Fuels must be purified; platinum catalyst used raises costs. |
Solid oxide (SOFC) | Hard ceramic compound of metal oxides | 1000°°ä | 60% | Up to 100 kW | Most common use is in large stationary power plants. | High temperature limits applications and electrolytes can crack. |
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